In order to account for session 0 isolation you need to use the following commands:
psexec -s -i 0 \\computername c:\reskit\procmon /backingfile c:\temp\procmon /quiet
and then to stop collection:
psexec -s -i 0 \\computername c:\reskit\procmon /terminate
It is critically important that you stop the procmon collection process by using the terminate command. If you simply kill the process or reboot while it is running the log file will be corrupted and unusable.